Adsorptive removal kinetics of anionic dye onto chitosan films doped with graphene oxide: An in situ fluorescence monitoring

dc.contributor.authorKahya, Nilay
dc.contributor.authorBener, Semira
dc.contributor.authorKaygusuz, Hakan
dc.contributor.authorEvingur, Gulsen Akin
dc.contributor.authorErim, F. Bedia
dc.date.accessioned2021-05-15T12:42:08Z
dc.date.available2021-05-15T12:42:08Z
dc.date.issued2018
dc.departmentMühendislik ve Doğa Bilimleri Fakültesi, Temel Bilimler Bölümüen_US
dc.descriptionErim, Fatma Bedia/0000-0001-9406-6681; Kahya, Nilay/0000-0002-7884-5113; BENER, SEMIRA/0000-0001-5340-068X
dc.description.abstractThe aqueous adsorption of a fluorescent dye (pyranine) onto crosslinked chitosan-graphene oxide composite films was studied. In situ fluorescence monitoring technique is introduced as easy and fast experimental technique to select optimal adsorbent conditions. The effect of ionic crosslinker on adsorption was studied with sodium tripolyphosphate, trisodium citrate, and sodium sulfate, respectively. Among the crosslinkers, it was realized that sodium sulfate crosslinked films showed a greater adsorption rate for pyranine than the other two types of crosslinked films. Recently, graphene oxide is of interest as a filler compound for many biopolymer applications due to its favorable thermal, mechanical and surficial properties. In the present study, graphene oxide incorporation increased adsorption rate of the dye and the mechanical strength of ionically crosslinked chitosan films. The adsorption behavior of the adsorbent was explained by a kinetic model. Samples were characterized using scanning electron microscopy, thermogravimetric analysis, swelling experiments and tensile testing method.en_US
dc.description.sponsorshipIstanbul Technical UniversityIstanbul Technical Universityen_US
dc.description.sponsorshipThis study is equally derived from the MSc thesis of Nilay Kahya and Semira Bener, and is funded by graduate research grants of Istanbul Technical University.en_US
dc.identifier.doi10.1080/00986445.2017.1423064
dc.identifier.endpage887en_US
dc.identifier.issn0098-6445
dc.identifier.issn1563-5201
dc.identifier.issue7en_US
dc.identifier.startpage881en_US
dc.identifier.urihttps://doi.org/10.1080/00986445.2017.1423064
dc.identifier.urihttps://hdl.handle.net/20.500.12939/899
dc.identifier.volume205en_US
dc.identifier.wosWOS:000435526800003
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.institutionauthorKaygusuz, Hakan
dc.language.isoen
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofChemical Engineering Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAdsorptionen_US
dc.subjectChitosanen_US
dc.subjectCrosslinkeren_US
dc.subjectGraphene Oxideen_US
dc.subjectPyranineen_US
dc.titleAdsorptive removal kinetics of anionic dye onto chitosan films doped with graphene oxide: An in situ fluorescence monitoring
dc.typeArticle

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